1

Particle in a Box

medium25 pts

Statement#

A particle of mass mm is confined to a one-dimensional box (infinite potential well) of length LL:

V(x)={0if 0<x<LotherwiseV(x) = \begin{cases} 0 & \text{if } 0 < x < L \\ \infty & \text{otherwise} \end{cases}

  1. Solve the time-independent Schrödinger equation inside the box
  2. Find the allowed energy levels EnE_n
  3. Find the normalized wave functions ψn(x)\psi_n(x)

Required Topics#

  • Time-independent Schrödinger equation
  • Boundary conditions
  • Wave function normalization
  • Energy quantization
  • Second-order differential equations

The Schrödinger Equation#

Inside the box where V=0V = 0: 22md2ψdx2=Eψ-\frac{\hbar^2}{2m}\frac{d^2\psi}{dx^2} = E\psi

Boundary Conditions#

  • ψ(0)=0\psi(0) = 0 (wave function vanishes at walls)
  • ψ(L)=0\psi(L) = 0 (wave function vanishes at walls)
  • 0Lψ(x)2dx=1\int_0^L |\psi(x)|^2 dx = 1 (normalization)

What to Find#

  1. Allowed energy eigenvalues: EnE_n (quantized energies)
  2. Corresponding eigenfunctions: ψn(x)\psi_n(x) for n=1,2,3,n = 1, 2, 3, \ldots
  3. Show that energies are proportional to n2n^2

Solution#

Solution coming soon.

Hints (4)

Topics Needed

schrodinger-equationinfinite-potential-wellwave-functions

Prerequisites

  • differential-equations
  • boundary-conditions
  • quantum-basics

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